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Our favorite places were a beautiful valley with white sand, and a refreshing Laguna at S 35° 41.643', W 070° 25.651' and the Laguna Aquas Calientes at S 35° 30.441', W 070° 31.990'. The latter is not actually a hot lake, but there are several small streams of warm water. We camped right at S 35° 30.129', W 070° 31.514', right next to a really nice hot pool.
Things to watch out for: although water was generally abundant, there are some spots where water is a bit more sparse (especially late in the season) and you might have to carry for up to one day. See Natalie's trip report for details. Additionally, earlier in the season there might be snow fields. The winter in 2023 had a crazy amount of snow, so even though we went in March we had a lot of water from snow melt and the two passes at 02D (S 35° 39.116', W 070° 26.016') and S 35° 33.137', W 070° 44.275' had steep snow fields. It was a bit sketchy, but okay. For the first pass, there are other options up, which may open up earlier. For the second pass, Option 2B traverses a lower pass (we didn't go there). A lot of hiking is on cross country, much of it on sand or gravel of different firmness. Sometimes you sink in, sometimes not. Flat or downhill travel is generally efficient, uphill is slow. Bring (mini)-gaiters, not just because of sand but also spikey plants. Also, sun protection is crucial, you won't have any tree for a week.
Logistics: Interbus (call them on WhatsApp: +56 9 9886 5872) runs a bus Mon-Fri from Talca to Medano (which is a bit further than la Mina). As of March 2024, this bus left at 12:30 and 19:00, returning to Talca from Médano at 7:20 and 15:30. From Médano hitchhike to the border checkpoint. It's not super easy, and you might only get as far as the furthest mine, roughly 5km before the border checkpoint. Alternatively, use a ride sharing app to go to the border checkpoint. We were able to get via multiple rides all the way to the border checkpoint, but it took some time (we arrived at 5.30pm). If you want to check out Laguna del Maule, tell the border guard that you're not crossing into Argentina, and they will let you pass. But the border checkpoint is closed at night (between 6pm and 9am?) and you're not supposed to cross it then. We quickly went to the lake and back before it closed.