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→By public transport and hitchhiking
Both companies have Facebook pages, in Spanish, where they publish their bus timetables
If you miss your bus to the national park and are short of time, you can hitchhike from Valdesina, which is a small settlement on the road between Molina and Radal. You can take a minibus or ("micro") to Valdesina. These minibuses leave from just outside Curicó bus terminal and make a stop at Molina bus terminal on the way. It's just a case of riding one as far beyond Molina as it will take you, and then getting off the minibus before it turns around and heads back the other way. If you can't find a minibus to Valdesina, then just hop on one that has a destination sign on the front that includes the place name "TRES ESQUINAS". These minibuses can at least drop you off on the Molina-Radal road -- specifically, in the settlement of La Palmilla, which is about three kilometres less far up the road than Valdesina. Either way, make it clear to the bus driver that you plan on hitchhiking to Radal/Las Siete Tazas/Parque Inglés, so that he knows where to drop you off.
Bear in mind that if you are visiting the national park, without a vehicle, outside of the peak tourist season, then even in the BEST case scenario, you will have to hitchhike into it from the village of Radal.